Secondary Atmosphere

A secondary atmosphere is an atmosphere that builds up from outgassing of a planet’s interior or surface chemistry after the primordial H/He envelope has been lost to stellar radiation or escape processes.

Composition drivers

Secondary-atmosphere composition is primarily set by the planetary interior’s oxygen fugacity:

JWST context

JWST has confirmed secondary atmospheres on some lava planets (55 Cnc e) while finding no detectable atmosphere on others (e.g., src-jwst-lhs-3844b-bare-rock-2026). The diversity in outcomes constrains secondary-atmosphere formation efficiency as a function of interior composition, stellar environment, and outgassing history.

Biosignature implications

Distinguishing a secondary atmosphere rich in CO₂ or SO₂ from a biogenic atmosphere is a key challenge for biosignatures interpretation. Abiotic outgassing can mimic some biosignature gases, requiring multi-gas context to discriminate (false-positive-biosignatures).